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Sieverts' law : ウィキペディア英語版
Sieverts' law

Sieverts' law, in physical metallurgy, is a rule to predict the solubility of gases in metals. It is named after German chemist Adolf Sieverts (1874–1947). The law states that the solubility of a diatomic gas in metal is proportional to the square root of the partial pressure of the gas in thermodynamic equilibrium.〔C. K. Gupta, "Chemical metallurgy: principles and practice", Wiley-VCH, 2003, p.273.〕 Hydrogen, oxygen and nitrogen are examples of dissolved diatomic gases of frequent interest in metallurgy.
== Justification ==
Sieverts' law can be readily rationalized by considering the reaction of dissolution of the gas in the metal, which involves dissociation of the molecule of the gas. For example, for nitrogen:
:N2(gas) 2 N(dissolved)
For the above reaction, the equilibrium constant, K, is:
:K^2 =
Where:
* C is the concentration
* p is the partial pressure
Therefore,
:C_N =

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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